Progress in Photovoltaics: Research and Applications | 2026; 34:367–395
Gernot Oreski, Chiara Barretta, Petra Christöfl, Paul Gebhardt, Karl-Anders Weiß, David C. Miller, Soňa Uličná, Michael Kempe, Laura S. Bruckman, Alessandro Virtuani, Hengyu Li, Brian Habersberger, Jeff Munro, Kristof Proost, Marcel Kühne
In recent years, photovoltaic (PV) encapsulant films marketed as polyolefins (POs), more specifically as PO elastomers (POEs) and thermoplastic POs (TPOs), have gained significant market share and are projected to become the dominant encapsulation films by 2030. Relative to other industries, there are significant misconceptions about the term PO in the PV industry. Both in the scientific literature as well as in sales and advertising, the terms PO, POE, and TPO are often misused to describe the same type of material with comparable properties, while in reality these may each consist of separate material classes.
A group of internationally leading experts therefore addressed the issue to improve clarity in the industry and avoid misunderstandings. This paper provides a comprehensive literature and market review, to showcase a broad range of PO and other ethylene copolymer encapsulants from recent studies and discusses the materials' properties to clarify what constitutes a “polyolefin.”
In addition, to promote a clearer comparison of encapsulant properties, we propose a two-dimensional taxonomy to categorize polymers used in module manufacturing. In terms of improving the reliability of solar PV modules, PO-based encapsulants have several advantages, but might come with disadvantages too. All this might prospectively impact adhesion properties of the encapsulant to other materials' interfaces (glass, cells etc.) and end-product quality. Because the track record of field-deployed PV modules containing PO encapsulants is limited, we hope to contribute to better material understanding and precision in communication in PV to secure quality.