SCIENCE | Volume 390 | Issue 6772 | 30 Oct 2025 | DOI: 10.1126/science.adx1745
Oussama Er-raji, Christoph Messmer, Rakesh R. Pradhan, Oliver Fischer, Vladyslav Hnapovskyi, Sofiia Kosar, Marco Marengo, Mathias List, Jared Faisst, José P. Jurado, Oleksandr Matiash, Hannu Pasanen, Adi Prasetio, Badri Vishal, Shynggys Zhumagali, Anil R. Pininti, Yashika Gupta, Clemens Baretzky, Esma Ugur, Christopher E. Petoukhoff, Martin Bivour, Erkan Aydin, Randi Azmi, Jonas Schön, Florian Schindler, Martin C. Schubert, Udo Schwingenschlögl, Frédéric Laquai, Ahmed A. Said, Juliane Borchert, Patricia S. C. Schulze, Stefaan De Wolf, Stefan W. Glunz
Achieving terawatt-scale deployment of photovoltaic technologies necessitates both cost-effectiveness and resource efficiency. Perovskite/silicon tandem solar cells represent a highly promising avenue, offering power conversion efficiencies (PCE) of up to 34.85% with minimal additional manufacturing costs. Their commercial viability depends on the integration of industry-compatible architectures, such as monolithic fully-textured tandems employing standard silicon pyramid sizes (>1 μm). In this configuration, the perovskite layer is deposited via a hybrid evaporation/spin-coating process, forming a structured interface that effectively minimizes optical reflection losses. Nevertheless, the PCE of these devices remains constrained by photovoltage and charge transport losses at the perovskite/electron transport layer (ETL) interface.
To mitigate these limitations, an optoelectrical simulation study guided the exploration of two interfacial passivation strategies: chemical passivation and field-effect passivation. The latter demonstrated a unique advantage in perovskite systems, where electron accumulation extends beyond the interface into the bulk absorber, enhancing conductivity and reducing transport losses. Experimentally, the application of 1,3-diaminopropane dihydroiodide (PDAI) at the perovskite/ETL interface yielded a PCE of 33.1%, an open-circuit voltage of 2.01 V, and improved operational stability of the devices, as tested in the Red Sea Coast. These findings affirm that large pyramid textures do not impede effective passivation, thereby supporting the industrialization of high-efficiency fully-textured perovskite/silicon tandem solar cells.