Dimethyl Ether – A Multi-Talented Fuel For Sustainable Mobility, Industry and the Energy Sector

Hydrogen and its derivatives, such as methanol and dimethyl ether (DME), are essential for the defossilization of the transport, industry and energy sectors. DME is a non-toxic gas with physical and chemical properties similar to those of propane and butane, the main components of LPG (liquefied petroleum gas, also known as camping gas or autogas). DME has a high energy density and could play an important role, particularly in the large-scale import of sustainable energy sources and raw materials for industry, which is necessary for Germany. The hydrogen storage capacity of DME is 47% higher than that of ammonia, which is currently the focus of attention as an H2 energy carrier. Due to its advantageous properties, DME is already widely used as a solvent, coolant and propellant. The global DME market currently comprises more than 5 million tons per year. New applications for DME, e.g., as a hydrogen carrier and platform molecule, offer great growth potential. Furthermore, DME can be liquefied at low pressures of a few bar and blended with fossil LPG at a ratio of up to 20%. The global LPG market comprises approximately 200 million tons per year, which means that blending alone creates a market potential for DME of 40 million tons per year. Furthermore, as a platform molecule, DME offers many possible applications as an intermediate product for the further synthesis of aviation fuels, gasoline and other refinery products.

Dimethyl ether (DME) – A Multi-Talented Fuel For Sustainable Mobility, Industry, and the Energy Sector
© Fraunhofer ISE

Where will Sustainable Dimethyl Ether be Used in the Future?

Dimethyl ether is a versatile energy carrier with high energy density. It can be used as a hydrogen carrier in an international hydrogen economy, but also as a feedstock for sustainable fuels or the chemical industry.

Dimethyl Ether as a Hydrogen Carrier

Dimethyl Ether as a Platform Molecule

Transport

LPG-Blending

Environmentally Friendly Building Block of the Future Hydrogen Economy: What Makes Dimethyl Ether so Sustainable?

  • DME is a non-toxic and environmentally friendly gas with a very low global warming potential. Its GWP100 is 0.3 CO2eq.
  • The water requirement for DME production is reduced by approximately 45% compared to ammonia. This is an increasingly important aspect, especially in light of water scarcity in energy-exporting countries.
  • The 47% higher hydrogen storage capacity of DME compared to ammonia is made possible by steam reforming of DME in the importing country.
  • If DME is used as a hydrogen carrier, a closed DME/CO2 cycle can be established, in which DME is exported from the producing countries and CO2 is imported.
  • DME has excellent combustion properties with a lower tendency to form soot, which is due to the chemical structure of the missing carbon-carbon bond.
  • DME increases resilience in energy supply because it is easy to liquefy and therefore easy to store.
  • Sustainable production: Fraunhofer ISE has developed a particularly efficient, resource-saving, and cost-effective process for DME production (INDIGO), which is significantly more efficient than the fossil-based process.

By using low-carbon hydrogen for the production of DME and, where applicable, simultaneously using CO2 from biogenic sources or direct air capture (DAC), CO2 emissions in transport, the chemical industry and the energy sector can be significantly reduced. Skillful process management also enables DME production as a negative emission technology.

Dimethyl Ether Technology Topics

DME offers advantages over other energy sources, but there are still gaps in research that need to be filled. These research questions concern the supply of CO2 (e.g., through direct air capture, DAC, and reverse water gas shift reaction, RWGS), synthesis gas (reforming, gas purification, adjustment of an optimal gas mixture (CO, CO2, H2). Furthermore, questions regarding the stability of the catalyst in the INDIGO process need to be answered and cost-optimized process concepts developed. With regard to the production of fuels and chemicals from DME, improved catalysts need to be identified and characterized and integrated into an optimized process. Another focus is on the development of active, selective, and stable catalysts for low-temperature DME reforming. In addition, one of the goals of our research activities is to develop an optimized, scalable reactor design, including process control and concepts for innovative DME reforming.

Learn more about our technology topics related to dimethyl ether

 

Dimethyl ether (DME) – production, synthesis products, and applications
© Fraunhofer ISE
Dimethyl ether (DME) – production, synthesis products, and applications

Further Information on this Research Topic

 

R&D Infrastructure

Laboratory for Sustainable Synthesis Products

In our laboratory for sustainable synthesis products we develop, test, characterize, and optimize processes, reactors, and materials for the synthesis of Power-to-X products, the production of hydrogen from sustainable synthesis products, and Direct Air Capture (DAC). 

Research Project

E-Fuels for the LÄND

CO2 Direct Air Capture and DME Synthesis as Key Technologies for E-Fuels

Research Project

EARTH2

Efficient and Resource-saving Transport of Hydrogen using Dimethyl Ether

Research Project

Power-to-MEDME

Production of Green Hydrogen Carriers in Chile

Research Project

LNG2Hydrogen

TransHyDE Project: Making LNG Terminals Suitable for Hydrogen-based Energy Carriers